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Liquid Bulk Shipping

Plasticizers: Classifications, Examples, Benefits, Uses, and Regulations

March 30, 2021 by luis uribe

PET Preform in PET bottles blowing. The plastic bottle blowing machine.Heating process for plastic bottle process.

If before now, you were unfamiliar with plasticizers, you’ll soon see that you know more about them than you thought. They are everywhere. Plasticizers are some of the most versatile chemicals used across many industries for their unique properties.

In this article, you’ll find everything you need to know about plasticizers, including:

  • What plasticizers are and what they are used for.
  • The classifications of plasticizers, and phthalate plasticizers, the most commonly used of these classes
  • The best way to ship plasticizers.

Plasticizers: What They Are and What They Are Used For

Plasticizers are organic chemicals that can improve the flexibility, viscosity, softness, friction level, and plasticity of materials. The materials that require the addition of plasticizers are often polymers, such as rubber and plastic. Using plasticizers in these polymers makes the materials easier to handle when they are being processed into end products. It also equips them for an end-user application.

A popular use case for plasticizers is polyvinyl chloride (PVC), a material that is used across various industries to make clothes, hoses, vinyl flooring, electric wire coatings, seats, and more. PVC, in its original state, is hard and brittle, which makes it unsuitable for most of the things we use PVC for. But once you add plasticizers to PVC, what you get is the multi-purpose PVC that we have today.

Another common application of plasticizers is in concrete formulations. Concrete formulations without plasticizers in them are a nuisance to handle. But plasticizers in concrete formulations make the concrete easier to work with.

Common Applications of Plasticizers

The most common application of plasticizers is in PVCs, and this is because of the massive market for plasticized PVC. Some of these applications include:

●      Coated Fabrics

Fabric makers often use plasticized PVC coatings to make their fabrics stronger, more durable, and weather-resilient. Some industries that use PVC-coated fabrics include the food, agriculture, architecture, sports, lifestyle, and defense industries. The fabrics themselves include tents, outdoor furniture, tarpaulins, and many more.

●      Film and Sheeting

The weather-resilient property of flexible PVC makes it a great material for making roofing membranes, swimming pool liners, advertising signs, and many more.

●      Wire and Cable

Flexible PVC has characteristics that make it useful in the electrical industry. It is an excellent electrical insulator, temperature resilient, and easy to handle. These properties then make it a perfect material for sheltering electrical conductors and insulating fiber optic cables.

●      Flooring

The strength of flexible PVC is once again relied upon in making flooring products. Some of these products include durable sheet flooring, luxury vinyl tile, vinyl composition tile, and vinyl-backed carpet tile.

●      Medical Products

Some medical product manufacturers also acknowledge and use flexible PVC to make products like blood bags, biohazard containment structures, IV tubing, and many more.

Classifications of Plasticizers

The most common method of classifying plasticizers is according to their chemical composition. Each chemical composition has properties that are peculiar to it, and we can easily imbibe these unique properties into base polymers to equip them for specific applications. For instance, some phthalate plasticizers are popular for their ability to retain their flexibility and durability for a long time. That is why they are used to make products like car upholstery and shoe coatings that require such characteristics.

According to the chemical composition classification, a lot of chemical families fit into the description of plasticizers. But the most common among them are:

  1. Adipate plasticizers (such as DEHA and DIDA)
  2. Benzoate plasticizers (such as benzoate esters)
  3. Bio-based plasticizers (vegetable oil plasticizers)
  4. Energetic plasticizers (such as BTTN, BDNPA, and DNT)
  5. Citrates plasticizers (such as ATBC, TOC, and ATOC)
  6. Phthalate ester plasticizers (such as DINP, DIDP, and DEHP)
  7. Trimellitate ester plasticizers (such as TIDTM, TINTM, and TEHTM)

And each of these classes possesses, in varying degrees, the ability to make polymers or resins:

  • Withstand cold temperatures
  • Easier to process when making them into end products
  • Softer and more flexible.

Apart from these general characteristics, there are still some classes that have peculiar characteristics that make them suitable for various specific purposes. However, we only dive into the deeper details of the most commonly used of these plasticizer classes: Phthalate Plasticizers

Hand of young male worker of large modern factory holding polymer granules in hand during industrial process

Phthalate Plasticizers

Phthalate plasticizers contain useful properties, including low volatility, weather-resistance, low solubility in water, and remarkable resistance to biodegradation. These properties make it useful for a variety of purposes. However, its compatibility with the PVC polymer is its trump card.

PVC is a widely used material for purposes that cut across various industries, from the sensitive food industry to the structural construction industry. And it is because of this compatibility that phthalate is the most commonly used plasticizer. Few plasticizer classes can achieve this level of compatibility, and it makes it hard for them to replace phthalates as the most common plasticizer.

By the way, phthalate is pronounced as “thalate”, with the “ph” silent.

There are many common examples of phthalate plasticizers, and each of them has advantages and limitations for the purposes we use them for. Some examples are:

1.    DIDP

Diisodecyl phthalate (DIDP) is an odorless and colorless liquid with high ortho-phthalate molecular weight. Its solubility spans across many organic solvents, but not in water. It has uses in different industries, including the automobile, electrical, and flooring and construction industries. Other things we use DIDP for include texture inks, anti-corrosion paints, and sealing compounds.

Benefits of DIDP

  • DIDP is known for improving and retaining the flexibility of polymers.
  • DIDP has a more lasting effect than other plasticizers, such as DINP.

Applications of DIDP

  • DIDP plasticizers have some properties that set them apart from other plasticizers. An example of such property is its low volatility. Thanks to this property, it can be easily processed and used in PVC. And that is why we use DIDP in products that would be exposed to high-temperature ranges.
  • Manufacturers also rely on the ability of DIDP to retain its properties in various weather and temperature conditions. And so we use it for outdoor products, such as roof waterproof materials, rain boots, and swimming pool liners.
  • Stability to heat and electrical insulation. These two properties of DIDP make the plasticizer suitable for making car interiors, electrical cords, PVC flooring, and many more. Other products that contain DIDP include pharmaceutical pills, cookware, furniture coatings, food wrappers, and many more.

2.    DINP

Diisononyl phthalate (DINP) is an odorless and colorless oily liquid with a high ortho-phthalate molecular weight. It’s soluble in hexanes and alcohols, but not in water. Its most common application is in the plasticizing of PVC. And although the primary application of DINP is in PVC plasticization, it also has other uses in lubricants, sealants, and paints.

Benefits of DINP

  • DINP plays a huge role in determining the properties that PVC products have. Examples of these DINP properties include durability, flexibility, and heat resistance.
  • DINP also possesses features that make DINP-based PVC products suitable for outdoor uses. One of such features is weather-resilience. It takes a long time before weather changes tell on DINP when it is used outdoors. Other properties include excellent thermal insulation, low volatility, resistance to degradation, and durability.
  • DINP also offers manufacturers the opportunity to control the amount of flexibility they want base materials to have. As a result, it makes the chemical additive suitable for various mechanical specifications.

Applications of DINP

  • DINP is used in making flexible PVC, a common material in the construction industry. DINP-based flexible PVCs are used to shelter sports arenas and buildings due to their durability, and water resistance.
  • The combination of DINP and PVC powder is used to make flexible flooring materials.

3.    DIBP

Diisobutyl phthalate (DIBP) is another phthalate plasticizer worth mentioning. Just like the other two phthalates above it, it is almost odorless and completely colorless. DIBP has low toxicity and poor solubility in water. It also has applications that cut across various industries.

Applications of DIBP

  • The remarkable heat and light stability properties of DIBP make it one of the best plasticizers for use in cellulose nitrate plastics. It is also the least expensive phthalate plasticizer that can be used in such plastics.
  • DIBP, like other phthalate plasticizers, can also be used in the manufacture of rubber and PVC to ease gelation.
  • Adhesives, paints, pulp, paper, lacquers, varnishes, and sealants often have DIBP in them.
  • Other applications of DIBP are in the printing inks, nail polishes, cosmetics, lubricants, clothing treatments, tapestry, floor carpets, and many others.
  • As a result of its similarities to DBP, DIBP can also be used in place of the phthalate plasticizer.

4.    DBP

Apart from being a plasticizer, the colorless and oily chemical is also an alpha-glucosidase inhibitor. Its toxicity levels range from zero to very low.

Applications of DBP

  • The main application of DBP is in the manufacture of flexible plastics.
  • Paint and plastic manufacturers use DBP as a medium for reaction during their chemical reactions.
  • DBP has uses in various types of adhesives, including hardening adhesives, general adhesives, and water-based adhesives.
  • Apart from its use as a plasticizer, DBP is also used in insecticides, antifoam agents, fragrance fixatives, and as a manometer fluid.

Limitations of DBP

  • DBP cannot be used in sensitive childcare products in quantities more than 1000ppm.
  • As a result of its low molecular weight, its applications have consistently been in a decline.
  • Its effects on the environment are detrimental. DBP can easily seep into the soil and contaminate the nearby water bodies.
  • The EU has banned the use of DBP in all cosmetic products while the United States places it on its Priority Pollutant List
  • Be careful when you hold a naked flame close to DBP, as it is combustible. You may need to be deliberate about igniting it before it ignites, though, as it does not ignite easily.

5.    BBzP or BBP

Butyl benzyl phthalate (BBzP or BBP) has a mild odor. But unlike many other phthalate plasticizers which are insoluble in water, BBP is moderately soluble in water. BBP was mostly used in the manufacture of vinyl products and other applications where its durability and flexibility are needed. However, the use of BBzP is greatly discouraged because of its toxicity.

Applications of BBzP

  • BBzP is most commonly used to make PVC flooring materials tiles because of its compatibility with PVC and its durability.
  • Other applications of BBzP are in the manufacture of conveyor belts used in food industries, automotive materials, and artificial leather.

Limitations of BBzP

  • BBzP is toxic. In fact, its use in various applications has continued to be in decline for over a decade now.
  • BBzB is banned in quantities more than 0.1% in sensitive childcare products, as its toxicity could lead to negative outcomes in the human body.

6.    DPHP

Dipropyl Heptyl phthalate (DPHP) is a viscous and odorless chemical that competes with other popular phthalate plasticizers, such as DINP and DEHP, in use for various applications. DPHP has remarkable plasticizing properties that make it an all-purpose plasticizer, especially in PVC materials.

Benefits of DPHP

  • It is one of the best plasticizers for PVC products where flexibility, high performance, and durability are in the job description.
  • Its weather-resilience makes it a suitable plasticizer in making outdoor products, such as roofing membranes.
  • Products that need to be durable, flexible, and resistant to high temperatures, such as automotive interiors and electrical wires and cables, also make use of DPHP.
  • DPHP does not pose any health or environmental risks.

Applications of DPHP

  • A DPHP-softened plasticizer is widely used in making all sorts of electric wires and cables.
  • Most of the plastics in automobiles have DPHP in them. Automobile manufacturers rely on this plasticizer because it allows them to get whatever shape, specification, and texture they want from their PVC. In fact, DPHP can even be made to feel and look like leather.

7.    DEHP or DOP

Diethylhexyl phthalate (DEHP), or dioctyl phthalate (DOP), is a low toxicity phthalate that is mostly used in medical devices. It is also one of the most commonly used phthalate plasticizers because of its inexpensiveness. DEHP is a water-insoluble plasticizer that you can find in materials used for making many consumer items.

Benefits of DEHP

  • DEHP is one of the most inexpensive plasticizers, making it suitable for applications where it is needed in large supplies. And that is why DEHP is used in most household items, such as shower curtains.

Applications of DEHP

  • The only phthalate plasticizer used in PVCs for medical devices is DEHP. Such devices include dialysis bags and tubing, IV catheters, and blood bags.
  • The inexpensiveness of DEHP makes it a suitable material in making many household products. Examples of products that may contain DEHP include personal care products, scented candles, laundry detergents, cosmetics, and air fresheners.

Limitations of DEHP

  • DEHP is a leachate. That is, it leaches into the environment from products where it is used.
  • Many countries ban DEHP because it is an endocrine disruptor, especially in the male gender.

8.    DIHP

Diisoheptyl phthalate (DIHP) is a water-insoluble plasticizer that has a variety of uses in industries, such as the construction industry. Unfortunately, its manufacture in the US and EU has been stopped because of its health and environmental hazards. However, it may still be used, albeit in small quantities.

Applications of DIHP

  • Screen printing inks have traces of DIHP in them, and some Australian manufacturers still use it as a specialist PVC plasticizer.
  • The durability of the plasticizer makes it a suitable plasticizer for making PVC flooring materials, including carpet backing, tiles, and coating plastisols.
  • Lubricating oils sometimes contain traces of the plasticizer.

Limitations of DIHP

  • DIHP may be responsible for some health complications, especially in unborn children. So, its use is highly discouraged.

9.    DIOP

The water-insoluble, colorless, oily, and slightly odored diisooctyl phthalate (DIOP) is a relatively safe plasticizer. Apart from being used in PVC, some countries even allow the phthalate plasticizer in materials that come in contact with food and other sensitive products.

Applications of DIOP

  • DIOP, like other phthalate plasticizers, is used to soften PVC. But its durability makes it a suitable plasticizer for making PVC jackets for building wire.
  • Apart from PVC, the plasticizer is also used in synthetic rubber and acrylic or cellulose resins.
  • The non-toxicity of DIOP plays a major role in making it one of the few phthalate plasticizers that are actually allowed to come in contact with eatables.

Limitations of DIOP

  • Although accumulated levels of DIOP in the body only have a few temporary discomforts, the plasticizer has the tendency to endanger an unborn child or impair fertility.
  • When DIOP seeps into the ground and gets to nearby water bodies, it is usually bad news for aquatic life in the waters.

10.                   DTDP

Ditridecyl phthalate (DTDP) is a high molecular weight phthalate plasticizer with remarkable performance under heat. It is an oily chemical that is slightly soluble in water. DTDP is also a relatively safe chemical that only has mild and temporary effects on health after exposure.

Benefits of DTDP

  • DTDP is one of the phthalate plasticizers that retain its property the longest during use.
  • The heat-resisting property of DTDP makes it suitable for materials that would be exposed to high-temperature uses.
  • DTDP may be used as an inexpensive alternative in applications where we use trimellitate plasticizers.

Applications of DTDP

  • DTDP is often the preferred phthalate plasticizer when PVC materials where excellent high-temperature stability are needed. These PVCs are then used in making electric conductor insulation in automobiles.
  • DTDP may also be used in lubricants, brake fluids, greases, and more.

11.                   DIUP

DIUP would just be like every other phthalate plasticizer if not for its resistance to fogging in vehicle interiors. This property alone makes it a crucial chemical in the automobile industry.

Benefits of DIUP

  • Compared to common phthalate plasticizers like DIDP and DINP, DIDP has a higher molecular weight. And an advantage of this is that the properties of DIUP last longer in products than the properties of the other two plasticizers
  • DIUP remains flexible and durable even in various weather conditions.
  • The non-toxicity of DIUP is a plus for it, as it is neither carcinogenic nor harmful to reproduction. Also, it is not an endocrine-disrupting chemical, making it safe for various sensitive products.
  • DIUP migrates very slowly. As a result, it hardly ever contaminates.

Applications of DIUP

  • DIUP is mostly used in automobile PVC products because of its low contribution to fogging.

12.                   DUP

Diundecyl Phthalate (DUP) is colorless, odorless, and oily. It is similar to DIUP in use and applications.

Benefits of DUP

  • DUP has high-temperature stability.
  • Like many other phthalates, DUP has a remarkable weathering ability.

Applications of DUP

  • The high-temperature stability of DUP makes it suitable for use in electrical wires, automobile leathers, and films.
  • DUP also has a low contribution to fogging, making it useful in the automobile industry for designing auto interiors.
  • DUP is also used in industrial lubricating oils as a base stock.
  • Other applications of DUP are in wall coverings, pool liners, water stops, floor mats, roofing membranes, and many more.

Disadvantages of Phthalate Plasticizers

Phthalate plasticizers bring a lot of advantages to the table, but they are not without their disadvantages. A lot of concerns have been raised over how safe they are, especially DEHP plasticizers. Some of these concerns include the following:

  • Some phthalates, despite their compatibility with PVC, do not bind chemically with polymers. And as a result, their particles often leach out into the environment.
  • Phthalates also accumulate in the human body from many sources, including PVC toys, car seats, vinyl shower products, and other products humans come in contact with daily. Medical practitioners have also found traces of the chemicals in nursing mothers, which are then passed to their babies through breastfeeding.
  • Studies also have it that DEHP is connected to sperm problems and low testosterone levels in men. Another study found phthalates to be responsible for negative impacts on neurodevelopment, leading to lower IQ, hyperactivity and attention issues, and more. This same DEHP is also carcinogenic, meaning that it encourages cancerous growth, and it is regarded as developmental toxins.

Advantages of Phthalate Plasticizers

The question on your mind may now be, “why do we use phthalate plasticizers if some of them can be this dangerous?” Here are some reasons phthalates plasticizers are still widely used despite the potential dangers some of them pose

●      Phthalates are inexpensive

Phthalates are economical. And since they are being used in large quantities and across various industries, cost-saving is one of their advantages.

●      Phthalates are effective

Phthalates do what they do well, making it hard for their potential replacements to overtake them. Phthalate plasticizers make polymers durable, flexible, weather resilient, and very compatible with the most commonly used polymer, PVC.

●      There is more supply of phthalates than their replacements

The potential replacements of phthalates are not in as much supply as phthalates. It then makes sense to use a material more abundant

Health and Safety with Phthalate Plasticizers

By now, you may also see the dilemma that phthalate-based plasticizers pose. They can be dangerous, but they can’t be done without. It is possible, however, to know how to handle phthalate exposure.

●      Wash Your Hands Regularly

This old trick has been keeping us safe for years, and it continues to do so. Wash your hands regularly to get rid of plasticizer traces on your hands.

●      Always clean dusty areas in your home

Some phthalate plasticizers don’t bond well with PVC. And so, the plasticizer particles can become loose and float around with the dust in the air. That is why you should avoid dusty areas as much as you can. Also always rid your house of dust by consistently vacuum cleaning dusty areas.

●      Don’t let kids play with plastics that are not toys

Toys made from plastic often contain minute traces of phthalate in them, and so are relatively safe for kids to put in their mouths. Any other plastics, however, should be kept away from their reach.

Still, on the safety topic, it is also important that industries where plastic PVCs are used handle the chemicals safely. And the safe handling of these chemicals starts from shipping them.

Energetic Plasticizers

This is another classification of plasticizers that is worth mentioning. Energetic plasticizers are used in fuels and propellants to improve their physical properties and specific yield. Examples of the energetic materials that require the use of energetic plasticizers are smokeless gunpowders and rocket propellants.

Energetic materials help us extract more energy from propellants, and this is why they are preferred to non-energetic plasticizers in this application. However, energetic plasticizers can be expensive and unsafe.

Examples of Energetic Plasticizers

The most common examples of energetic plasticizers are:

  • Bis(2,2-dinitropropyl)acetal (BDNPA)
  • Bis(2,2-dinitropropyl)formal (BDNPF)
  • Butanetriol trinitrate (BTTN)
  • Diethylene glycol dinitrate (DEGDN or DEGN)
  • Dinitrotoluene (DNT)
  • Nitroglycerine (NG). NG may be more familiar to you as “nitro.”
  • Triethylene glycol dinitrate (TEGDN or TEGN)
  • Trimethylolethane trinitrate (TMETN or METN)
  • 2,2,2-Trinitron Ethyl 2-nitroxyethyl ether (TNEN)

How To Ship Plasticizers

Plasticizer shipping is as important as the chemicals themselves. This is because the industries where they use plasticizers rarely buy them in packaged bits. That approach would be costly. Instead, they have the plasticizers shipped to them in bulk through chemical tankers, where they can unload them into their reservoirs and put them to use from there. That is the cost-effective way of shipping bulk fertilizers. This shipping method, however, is not without its challenges.

Regulations Around Shipping Plasticizers

The greatest challenge with shipping plasticizers is the toxic nature of the chemicals. Many of them are rated hazardous materials. And as such, the regulations that pertain to shipping hazardous materials apply to them as well.

But the problem here is that these regulations are many, and everyone involved in the shipping of the chemicals has, at least, a handful of regulations to adhere to. Although this is expected when you consider the hazardous nature of many plasticizers, the regulations can be inconvenient to keep up with. Especially since the regulatory bodies in charge of the regulations constantly update the regulations.

Plasticizer Shipping Conditions

Plasticizers, like many other chemicals, have their ideal conditions as regards pressure, temperature, and others. This could pose a challenge to shippers or companies who don’t have the equipment to keep the chemicals in their ideal conditions during transit. And transporting the chemicals under any other conditions apart from the ideal conditions could be catastrophic.

In addition, plasticizers, such as DBP, need to be desensitized with other chemicals before they can be safely transported.

caucasian scientist in blue lab suit and gloves stand on platform and look in the chromed tank, clean laboratory, tank on front

Shipping Your Bulk Plasticizers with Total Connection

If you had to ship your bulk plasticizer on your own, you would have to adhere to all the related regulations, no matter how many or inconvenient they are. It is not unheard of that some companies even have departments that handle their hazardous plasticizer shipments. The downside to this is that it requires more labor and more expenses for the company. You may also need to procure customized bulk chemical tankers to keep the plasticizers in good condition during transit.

But who said you have to do it all on your own?

Total Connection is a logistics company that prides itself in the shipping of liquid bulk anything. We ship chemicals pertaining to various industries, including the oil and gas, food, agriculture, and construction industries. The nature and quantity of the chemicals don’t even matter. We ship them in their kinds and quantities.

Total Connection has been shipping hazardous plasticizer chemicals for about three decades now, and we have an over-the-top success rate. Despite the excellent success rate, we have insurance backing up any chemical that we ship, as we don’t leave anything to chance. What this means for you is that you would be risking next to nothing, and neither would you be doing much. You wouldn’t even have a lot of HAZMAT regulations to worry about until the chemicals are in your custody.

All you need to do is contact us through the brief quote form below for your plasticizer chemical shipping, and we’ll take it from there.

Filed Under: Liquid Bulk Shipping

Oil and Gas Exploration Chemicals Shipping and Logistics

March 18, 2021 by luis uribe

Offshore Jack Up Drilling Rig Over The Production Platform in The Middle of The Sea

Oil and gas exploration and production involve many complex processes and phases. And at their core, oil exploration and production are expensive and destructive. Spillages could contaminate water bodies near the drilling sites. Mishandling of materials on the oilfield could be disastrous to the operators nearby. Heavy drilling could cause minor earthquakes around the drilling sites. The list of things that could go wrong goes on and on.

But with oil and gas exploration and production chemicals, the processes involved in extracting oil from the ground become more economical and less destructive. This article discusses different oil production chemicals and what they contribute to the production process. It also discusses how to ship these chemicals to the oilfield, the challenges that come with shipping them, and the solution to these challenges.

Different Chemicals Used in the Exploration and Production of Oil and Gas

Engineers set up a rescue tripod at the top of an abandoned oil well on the West Coast before sending workers into a confined space.

Here is a list of chemicals used in oil and gas exploration and production. These chemicals have various functions that make them crucial from the extraction of crude oil from the ground to refining it into different forms for public use.

1.    Acetic Acid

Acetic acid is involved in many oil and gas exploration and production applications. But one of the most widely used cases is in well stimulations. And its well stimulation applications are further divided into two. The first is hydraulic fracturing, and the other is matrix acidizing.

During hydraulic fracturing, drilling site operators inject drilling fluids containing the pungent-smelling acid at high pressure and in tight formations into wellbores. The drilling fluid cracks the oil reservoir at the bottom of the wellbore. But the acetic acid in the fluid makes the oil flow with ease during extraction.

Matrix acidizing, the other common application of acetic acid, involves the use of acetic acid to clear hindrances in the wellbore while keeping the reservoir intact. The acid is most effective when the hindrances are carbonates or limestone.

2.    Borates

Borates have applications across various phases of the exploration and production of oil and gas. The versatility of the chemical makes it one of the most relied upon chemicals in the oilfield. One area of application of borates in the oilfield is its use as a retardant for the cement used in supporting the wellbore after drilling. Another use that drilling site operators put borates to is the regulation of the viscosity in the drilling mud being injected into the wellbore.

Also, sodium perborate oxidizes hydrogen sulfide — a naturally occurring hazardous gas in the oil and gas industry — into less harmful sulfur or sulfate. And not only that, but it also attacks the bacteria that causes the natural formation of harmful hydrogen sulfide. Other uses of borates in oil and gas exploration and production include the regulation of pH and viscosity levels.

3.    Calcium Chloride

Just like the other chemicals on this list, calcium chlorides have functions that cut across different phases of oil and gas exploration and production. But its primary function is in maintaining and establishing the wellbores. It goes along with the drilling fluid mixture into the wellbores to lower the higher underground temperatures while also lubricating the drilling bits.

Calcium chloride also serves as a workover fluid to get rid of unwanted solids from the oil wells.  Other uses of calcium chloride in the oilfield include the acceleration of concrete formation time and helping to maintain pressure levels in the wellbore.

4.    Choline Chloride

When drilling a wellbore through clay soil, there is the need to stabilize the soil to stop it from swelling and destroying the oil well. That is what we use choline chloride for at the drilling site. And not only is it effective, but it is also inexpensive and safe.

There are other clay stabilizer alternatives, but oilfield operators often prefer choline chloride for many reasons. One of them is that the chemical remains useful even in the deeper levels of the oil well. It is also compatible with other chemicals used in the drilling fluid, including calcium chloride, cross-linkers, breakers, etc. Another reason choline chloride is the preferred clay stabilizer in many drilling sites is that it works in all drilling environments.

5.    Ethylene Glycol

Gas hydrates occur naturally during oil and gas production. They form when natural gas and free water meet at high pressure and low temperature. The problem with these hydrates is that they look like ice. And like ice, they can clog flow lines. Depending on the wellbore design, the drilling fluid composition, operating regime, and other factors, hydrate formation could be a massive problem in oil and gas production. But thanks to gas hydrate inhibitors like ethylene glycol, we have a solution to these hydrate formations. Ethylene glycol serves as an antifreeze agent which prevents the hydrates from clogging up the flow lines.

6.    Formic Acid

Formic acid is a common well stimulation treatment chemical. But unlike other well stimulation chemicals, such as hydrochloric acid, formic acid hinders the corrosion of metal pipes in wellbores with temperatures above 392°F. And when it corrodes steel pipes, it does so uniformly so that it reduces pitting.

7.    Guar Gum Powder and Slurry

Guar gum is basically the seed of a guar bean, while guar slurry is made from the guar bean itself. But their uses transcend the fields of agriculture into the oilfield. In oil and gas exploration and production, guar gum is used in various phases, including mud drilling, oil well fracturing, and oil well stimulation.

Oilfield operators add guar gum to drilling fluids to thicken the mixture before injecting it into the wellbore to fracture the oil reservoir. And one of its primary functions is to ease the drilling process while reducing fluid loss. Guar is also used as a suspending and stabilizing agent in drilling fluids. In addition, the viscosity of the drilling mud benefits from the regulating property of the guar.

Some reasons why guar gum powder is a favorite in many drilling sites are that it quickly hydrates in cold water, it is harmless, it is biodegradable, and environmentally friendly.

8.    Hydrochloric Acid

Hydrochloric acid plays a crucial role in oil and gas exploration. After drilling has been done, hydrochloric acid and water are pumped into the wellbore to get rid of cement debris that was left from the previous drilling princess. The acid also contributes to the opening of fractures in underground oil reservoirs.

9.    Phosphoric Acid

Phosphoric acid does not have a lot of direct functions in the oilfield, but we can make phosphate salts which are very useful in oil and gas exploration and production with it. Disodium pyrophosphate, for instance, is used as a dispersant in drilling fluids. Trisodium phosphate (TSP) is effective for degreasing. Sodium acid pyrophosphate (SAPP) is used as a clay flocculant and also to treat cement contamination. And a lot of phosphates can be used to cause the precipitation of calcium in water-based drilling muds.

10.                   Potassium Hydroxide

Another name for potassium hydroxide is caustic potash. Caustic potash has uses on the oilfield that range from pH and alkalinity regulation in potassium-based water drilling muds to clay stabilization. But like many other oil and gas exploration and production chemicals, it requires adequate training and equipment to be handled. It releases heat when you dissolve it in water, making it hazardous and dangerous when mishandled.

11.                   Sodium Carbonate

Calcium is an element that is naturally present in many water formations. And it is bad news for drilling sites, as it can cause clay flocculation and drilling fluid loss. High filtrate calcium is another form of calcium that could cause calcium-sensitive additives in drilling muds to precipitate. A solution to this is the use of sodium carbonate or soda ash treatment.

Soda ash is effective in treating calcium ion contamination in seawater and freshwater muds, while sodium bicarbonate (baking soda) is used to treat cement contamination in wellbores.

12.                   Sodium Hydroxide

Sodium hydroxide (also caustic soda or Lye) regulates the alkalinity and pH in water drilling fluids. Other applications of caustic soda in oil and gas exploration and production are in the reduction of lime solubility and in the increase of how fast dispersed clays are hydrated.

Caustic soda, like caustic potash, releases heat when dissolved in water. As a result, it is hazardous and requires adequate training and equipment to handle.

Shipping Oil and Gas Exploration and Production Chemicals

The shipping of oil and gas chemicals is best left for liquid bulk tankers, which must be commandeered by experienced carriers. There are a lot of complex processes involved in transporting these chemicals. And because of the diverse natures of these chemicals, it would be disastrous to handle their shipping in a one-size-fits-all manner. For instance, some chemicals don’t like agitation, so the tanker that holds them must be the right size for the volume being transported. Some other chemicals are best transported at a controlled temperature, calling for the need for in-transit heat chemical tankers.

The Challenges of Shipping Oil Production Chemicals

Here are some challenges the come with the shipping of oil production and exploration chemicals

●      Some chemicals are hazardous materials (HAZMAT).

The first challenge with shipping oil and gas exploration and production chemicals is that many of these chemicals are hazardous materials. The United States does not joke about the transport of these hazardous materials, and rightly so. An accident involving a caustic chemical near a water body, for instance, could raise the temperature of the water and cook the fishes inside. An accident involving corrosive acids could further lower the chances of survival for the tanker carrier and anyone else closeby. These, and many other scenarios, are disasters that are peculiar to the transport of hazardous materials.

Reacting to the potential dangers that accompany the transport of these hazardous chemicals, the United States Department of Transport has a long list of regulations that must be adhered to. But to be honest, adhering to them can be inconvenient, especially for an inexperienced carrier.  And so, the hazardous nature of the chemicals becomes a headache during the shipping of the chemicals.

●      The remote locations of many oilfields.

The remote locations of many drilling sites is another challenge that the carriers of oil and gas production chemicals face. This is because most of these drilling sites have unforgiving terrains that are hard to maneuver around with thousands of gallons of possibly hazardous chemicals in your trailer. An inexperienced carrier could become even more confused if the drilling sites are not on Google Maps, and they are left to find their way themselves.

●      Unreliability of the logistics company.

The reliability of the logistics company you choose to ship your oil and gas production chemicals is as important as the chemicals themselves. Any logistics company serving the oil and gas industry has to be reliable and flexible enough to handle urgent shipments, miscommunications, and order cancellations. These situations are common on this side of the world. But the absence of reliable logistics partners could affect operations at the drilling site.

How Total Connection Eases the Shipping of Production Chemicals for the Oil and Gas Industry

As many challenges as there are with shipping oil and gas exploration and production chemicals, a chemical shipping company can solve most of them. Now, we aren’t just talking about any kind of chemical logistics company, but one with enough experience and expertise to get the job done. A perfect example is Total Connection oil and gas chemical shipping company.

Total Connection is one of the best in the business of shipping oil and gas chemicals. The company relies on almost three decades of experience and expertise to mitigate all unnecessary risks and expenses that accompany oilfield chemicals shipping. It is robust enough to handle all your oilfield chemical needs, yet flexible enough to handle unforeseen circumstances without hitches. And with crucial partnerships with major oilfield chemical manufacturers, Total Connection can cut the excesses out of the supply chain and offers you chemical transportation at the lowest reasonable rates.

You too can find out why you should join many other oil companies in trusting us with your chemical shipping when you fill out the quote form below. Our kind experts will get back to you in no time.

Filed Under: Liquid Bulk Shipping, Oil and Gas

Shipping Lubricants and Fuel Additives

March 16, 2021 by luis uribe

Horizontally located cylindrical tanks with oil products and fuel for equipment. Installed in one row. Silver gray. Warehouse for the storage of fuel and lubricants. At the bottom of the tanks taps for fuel recruitment.

Friction. One of the major villains where machinery is concerned — which is just about anywhere you could think of. Able to shorten the lifespan of engines and machines by years. And in industries like oil and gas and the automobile where the machines used are usually heavy-duty, expensive, and hard to install, machine replacements are a plague to avoid. But we’re not defenseless against friction. We have lubricants and their additives.

Lubricants and their additives are some of the most widely used chemicals across all industries in the world. As long as we rely on machines to get things done, we’ll always need lubricants to preserve the lives of these machines.

This piece is about everything you need to know concerning lubricants and their additives, starting from:

  • What lubricants are and what lubricant additives are.
  • The different lubricating fuel additives that there are.
  • The challenges involved in shipping lubricating additives.
  • And how to mitigate the risks involving the shipping of lubricants and lubricant additives.

What are Lubricants

Lubricants are substances that reduce friction between the surfaces in contact and in relative motion to each other. Without lubricants, friction could cause the wear and tear of the surfaces in contact. But with lubricants in place, the surfaces simply slide over each other so that wear and tear are controlled or reduced. Apart from reducing friction, lubricants also have other functions that are crucial to preserving the lifespan of machines. These functions include suspending and cleaning, and keeping metal surfaces from corroding.

All liquids can serve as a lubricant, thanks to their nature. But each has varying levels of success when it comes to friction reduction. The ones that offer the best performances are called lubricants. And for each lubricant, there are ways to extract more lubricating effectiveness from it. This brings us to our next chemicals.

What are Lubricating Fuel Additives

Cuts in the enterprise, cutting a tooth into gears of a gear wheel.

Lubricants often consist of two key components. The first is the base fluid, which is the fluid that does the lubricating. The other is the lubricant additive.

Lubricant additives do one of two things when you add them to lubricating oils. They either enhance a property of the base fluid or add a new property to the base fluid. Some properties that base fluids already have in them include oxidation resistance, pour point, viscosity, and viscosity index. And the right additives can enhance all these properties. But some properties that the additives bring to the base fluid are corrosion control, anti-wear performance, and suspending and cleaning ability.

Today in industries like the automobile and the oil and gas, lubricating additives are right at the top of their list of most important chemicals. This is because of the remarkable uses of lubricating additives, especially in preserving the lives of engines. There are various additives that solve problems plaguing engines. Some of these problems include corrosion, the coagulation of soot and other particles, and acidic combustion of some products.

The Different Kinds of Lubricating Fuel Additives

These are some additives that are most commonly in use. We’ll classify them by their functions. Although some of these additives are multifunctional, we’ll categorize them according to their primary functions.

1.    Friction Modifiers

Friction additive modifiers are closest in function to the base lubricating fluid in that they contribute to friction reduction. When you apply a lubricant that contains a friction modifier additive, the additive forms a long-lasting low-resistance lubricant film. This is then absorbed into the surface of the machine.

Other functions of friction modifiers include wear reduction at low temperatures that render other anti-wear agents inactive, and fuel efficiency enhancement. Some popular materials used as friction modifier additives include the derivatives of long-chain fatty acids (and the fatty acids themselves) and molybdenum compounds.

2.    Anti-Wear Agents and Extreme Pressure Additives

Before these additives were used, all engine manufacturers could do to reduce wear in their engines was to limit the load on the machines. The more load there was, the more likely it was that the engines experienced wear. Then anti-wear agents and extreme pressure additives came around. These chemicals would decompose on heating into surface-active compounds that form thin films on surfaces that reduce wear. Zinc dialkyl dithiophosphate (ZDDP) is one of the most common anti-wear agents we use in engine oil today.

3.    Antioxidant Additives

It is important that lubricants are resistant to oxidation, especially when they’re used in engines. Lubricants are basically hydrocarbons, and when you expose them to heat and oxygen, they oxidize quickly.

To make matters more complicated, engines are nothing but oxidation zones. They contain metal parts, such as iron and copper, which are exceptional oxidation catalysts. So, there is the need for lubricants, especially engine oil, to be oxidation resistant to a good extent. And that is where antioxidant additives come in.

Examples of lubricating oil antioxidant additives include alkylated diphenylamines, hindered phenols, organomolybdenum compounds, dithiocarbamates, and ZDDP.

4.    Antifoam Agents

Foaming is an effect of lubricants that is completely frowned upon. Foaming of lubricant makes the lubricant more susceptible to oxidation when it mixes with the air. It can also lead to cavitation damage and insufficient oil circulation. And when all these happen, the lubricant loses its effect. Depending on the various applications of the lubricants, foaming can be tolerated at different levels. What antifoam agents or defoamant additives do is that they make the small air bubbles coalesce into bigger air bubbles, which float more easily to the surface. Here, they are let off as air.

5.    Rust and Corrosion Inhibitors

For rust to occur, moisture must be present. Intuitively, one of the ways to prevent rust is to prevent moisture. And that is exactly what rust and corrosion inhibitors do. Rust and corrosion inhibitors are compounds that attach themselves to the surfaces of metals. They then form strong film layers that inhibit the passage of water to the surface of the metals. Common examples of these additives include alkaline earth sulfonates and amine succinates. The only complication that is involved in using rust inhibitors arises when the additives form emulsions with water. That is why rust inhibitor-lubricant mixtures must be carefully selected.

6.    Detergent and Dispersant Additives

One of the properties of lubricants, especially automobile lubricants, is how they can suspend unwanted particles when they degrade through oxidation or thermal means. This category of additives helps the lubricants to control the formation of deposits by enhancing the suspension of unwanted products.

The Challenges of Shipping Lubricants and Lubricating Fuel Additives

In massive areas of application, such as in the oilfield, these chemicals are needed in bulk. And stainless steel tankers are delegated to transporting them. But there are some challenges that come with shipping these additives.

●      Some Additives are Hazardous Materials

Additives that have been categorized as hazardous materials are usually difficult to ship. Every party involved in shipping them — right from the manufactures to your company, the end-user — must adhere to an unending list of rules and regulations. Although these regulations are important because of the hazardous nature of the chemicals, they can still be inconvenient to follow. Keeping track of the regulations can also be an inconvenience, as the regulatory bodies keep updating them often. Without an experienced hazmat team to handle the shipping of these hazardous materials, the inconvenience would be the least of your problems. Things could easily spiral out of control, landing you in unnecessary expenses and trouble with regulatory bodies.

●      Remote Oilfield Locations

Many oilfields are far away from civilization. And while it is commendable to take activities such as oil drilling far away from communities, getting products and materials to the drilling sites could be a hard nut to crack. The roads leading to many of these oilfields cut across harsh terrains. And when an inexperienced carrier fails to make their way around the terrains with thousands of gallons of hazardous materials in their trailers, there isn’t a more catastrophic recipe for disaster.

●      Lubricating Additive Shortage

Having relied on many of these additives for centuries, we are now running low on the supply of these chemicals as the demand for them increases. As a result, acquiring the additives becomes difficult, becoming a treasure that only the big guns can possess.

How to Ease the Shipping of Lubricants and Lubricant Additives with Total Connection

Oil drilling derricks at desert oilfield. Crude oil production from the ground. Oilfield services contractor. Oil drill rig and pump jack. Petroleum production, natural gas, liquids, NGL, additive.

The experience we at Total Connection have is enough to completely solve most of those challenges. Total Connection is a logistics company that has mastered the shipping of oilfield chemicals. We have had about three decades of experience orchestrating the transport of all kinds of oilfield chemicals with enviable success.

Our carriers are experts at transporting your hazardous chemicals, as we choose them after rigorous selection processes before investing massively in training them. As a result, you’d be risking nothing at all when you ship your chemicals with us. Your company wouldn’t even need to worry too much about adhering to hazmat regulations because we’ll handle them for you (except for when they are in your possession).

In addition, we have built a network of partnerships with major suppliers and manufacturers of all oilfield chemicals. No matter how scarce or in short supply the chemical you need is, all you have to do is to fill the quote form below. Our experts will reach out to you, and soon enough, your chemicals will be on their way to your drilling site.

Filed Under: Liquid Bulk Shipping, Oil and Gas, Uncategorized

Shipping Emulsifiers and Demulsifiers

March 8, 2021 by luis uribe

Emulsifier Chemicals Stored in IBC tote containers

The oil drilling process involves many delicate sub-processes. Failure in one of these processes may lead to a cascade of failures across other processes. It is for this reason that oil companies do not tolerate failure in the oilfield at any point. And to make sure of this, oil producers rely on certain tools, materials, and chemicals to sustain a high level of productivity, and ultimately, profitability. Each tool, material, or chemical mitigates the failure of any process by solving problems that arise during the extraction of crude oil from the ground. But the problem that chemical demulsifiers solve is one of the most crucial in the oilfield.

This article takes you through:

  • First, why we need demulsifiers in oilfields, where we discuss the problem that demulsifiers solve.
  • It then tells you what demulsifiers are and how they work.
  • And just like other oilfield chemicals, it has to be shipped in bulk. So, you’ll see how to ship chemical demulsifiers in bulk.

Why We Need Demulsifiers in Oilfields

One of the major problems that have the potentials of reducing expensive oil drilling efforts to naught is water contamination of oil. During the extraction of oil from the ground, oil is not the only chemical that makes it out. Crude oil comes in a mixture containing various compounds, including water. But we don’t need the water. It would be pointless to invest billions of dollars just to pump water from the ground when what we need is oil. Hence, the need to further separate the crude oil from the water.

Water in oil is a problem because;

  • It may lead to the corrosion of oil storage components and tanks. Electrolytes are a crucial requirement for corrosion, and water makes a perfect electrolyte at some temperature ranges. And when corrosion attacks oil storage components, it could lead to a reduction in the quality of the oil in the storage tanks. It could also damage the components, leading to unnecessary replacement costs.
  • Another reason why water contamination of oil is bad news is that water reduces the lubricity of oil. And this increases the possibility of damage to the mechanical components that use the derivatives of the oil (such as gasoline, and diesel).
  • Since water is more susceptible to temperature swings than oil, having a lot of water content in oil makes it hard or impossible to store or further process the oil.
  • Water is also a growth enabler for slimy microbial growth. These growth clog filters and holes that crude oil should pass through.

These challenges lead to the water contamination of oil. And because of the potential complications that water in oil causes, there is a need to reduce the water content in oil. But the solutions depend on how the water exists in the oil.

Water either exists in oils either as an emulsion or free water. An emulsion is a uniform mixture of water and oil (two naturally immiscible liquids). Free water is water that visibly separates from the oil, thereby forming layers of oil and water. While mechanical filtration and separation techniques may work on free water, they are ineffective for emulsions. But with the use of demulsifiers, we can effectively separate water from the oil, irrespective of how the water exists in the oil

What are Demulsifiers

As the name suggests, demulsifiers remove emulsions. Emulsions forms when water and oil — two normally immiscible liquids — remain stably mixed. Demulsifiers discourage the water in oil emulsion and ensure that the particles of either liquid are separate enough that mechanical separation techniques become feasible. In other words, demulsifiers encourage the formation of free water that is then easy to remove through the use of mechanical methods.

How do Demulsifiers Work?

Demulsification is the breaking down of water-in-oil emulsions. These emulsions are liable to form naturally from the oil well. Naturally occurring emulsifiers, asphaltenes and resins, make sure of this. These agents encapsulate the particles of water in interfacial films that make them more stable and likely to remain mixed in crude oil. So, what demulsifiers do is that they reverse the effect of the emulsifying agents by destabilizing the water in oil emulsions. They achieve this by breaking down those interfacial films to make the water separate from the oil.

One of the reasons the naturally occurring water in crude oil emulsions are so stable is that the water mixes with the oil at the minute particle level. Micro and nano particles of water combine with oil particles before being uniformly dispersed all around the liquid. These uniform dispersion and particulate mixing make separating these liquids difficult for mechanical separation techniques.

Processes Involved in Demulsification

Demulsifiers go about breaking the emulsions in two major processes. The first is the flocculation or aggregation of scattered water particles. This process makes water droplets or particles come close to one another. But this does not necessarily mean the water droplets have separated from the oil. The interfacial films that attach the water particles to the oil particles are still yet to be destroyed. This first step is just the part where the particles coagulate.

The second step is coalescence, and this is where the water particles coalesce. The interfacial films that were keeping the water and oil in emulsion weaken to the point of breaking. Little water droplets and particles then come together to form heavier droplets that easily settle down to the bottom of the reservoir through sedimentation. But if there is no way to remove the water sediments from the bottom of the reservoir, oil producers use a process called creaming to make the water float to the top.

The Use of Chemical Demulsifiers

There are many ways to achieve this emulsion destabilization. Heating crude oil is one way to go about it. Decreasing the agitation of the oil is another effective way to destabilize the emulsion formation. Other methods include the removal of solids that have the tendency to keep emulsions stabilized, and increasing the time the emulsion spends at treating temperature. But the use of chemical demulsifiers is still the most popular of these methods.

Chemical demulsifiers, like emulsifiers, are also surface-active agents. Only that demulsifiers break down the interfacial films that keep the emulsions stable. They also encourage the coalescence of the water droplets. The only tricky part about using chemical demulsifiers is the complexity of choosing the best demulsifier for water-crude emulsions because of the various contents of the crude oil.

The fact that chemical demulsifiers are the most popular for demulsification doesn’t mean the other methods are unimportant, however. In fact, many oil producers make use of at least two demulsification methods during the processing of crude oil.

Advantages of Using Chemical Demulsifiers in the Oilfield

Here are some benefits that chemical demulsifiers have over other demulsification methods

●      Increased energy content

The ultimate goal of the oil and gas industry is to produce energy. It only makes sense that we try to extract as much energy from every drop of oil we have painstakingly extracted from the ground. And the use of demulsifiers for the separation of water from oil takes us closer to this goal.

Water displaces a corresponding volume of crude oil. And since oil is the main energy content of the mixture, the more water we have in the oil, the less energy content we can extract from the crude oil.

●      Allows for the use of mechanical separation methods

Once demulsifiers separate the water particles from the oil particles, it becomes easier to use mechanical techniques to separate the water content from the oil. This is especially beneficial, as the mechanical separation devices are most effective when the water is in free water from or unstably emulsified.

Tanker truck shipping liquid bulk emulsifier chemicals.
Tanker Trucks are used to ship emulsifier and demulsifier chemicals in liquid bulk over the road.

The shipping of Chemical Demulsifiers

It is difficult for oil producers to do without chemical demulsifiers at the oil drilling sites. As a result, oil companies invest as much into the shipping of the chemicals as they invest in the chemicals themselves. And when the chemical demulsifiers are needed in bulk, as they are often needed at drilling sites, the best way to ship them is through the use of stainless steel liquid bulk tankers.

Challenges of Shipping Chemical Demulsifiers to Oilfields

Shipping chemicals to oilfields always comes with challenges. Some, you may be able to prepare for. Others could only have been anticipated by experienced carriers.

For instance, the roads in many oil drilling sites may sometimes prove tricky to maneuver for inexperienced carriers. This inexperience may not be a problem until these carriers get involved in accidents with their millions of dollars’ worth of cargo. This issue is often common in massive oil drilling sites.

Another challenge that confronts the shipping of chemical demulsifiers — and any oilfield chemical for that matter — is the amount of work and planning that goes into the logistics and distribution management system of the chemicals. Ideally, this system is supposed to manage out-of-stock situations and optimize cost. But this system itself needs a lot of hands on deck to work smoothly. For instance, a typical oil company supply chain would include shipping warehouse managers, inventory supervisors, purchasing directors, site foremen, third-party freight managers, and many more. The major challenge here is that all these parties must work perfectly as a team, as miscommunication from one party could be catastrophic.

These challenges are only a few of the things that could go wrong with the shipping of chemical demulsifiers to oilfields. And with each challenge comes a level of risk. Risks that could cost your oil company millions of dollars as well as its reputation. However, partnering with an experienced oilfield chemical logistics company, such as Total Connection, will help you cut down on the risks that these challenges expose your company to.

Shipping your Liquid Bulk Chemical Demulsifiers with Total Connection

Total connection logistics offers you competence, reliability, and experience. And the company has had almost three decades to hone each of these services to best suit your business. What you get is a logistics company that is consistent with the effective shipping of your oilfield chemicals at costs that are best suited to your company. In our years of service, we have worked with both the consumer and supplier ends of the oilfield chemicals logistics. And we have built a network of partnerships that promises a lot of benefits to our clients.

Your business too can enjoy reliable chemical demulsifier shipping while cutting out excessive costs and unnecessary risks when you leverage our network of partnerships. You can start by simply filling out the short quote form below.

Filed Under: Liquid Bulk Shipping, Oil and Gas

Ship Surfactant Chemicals

February 24, 2021 by luis uribe

ship surfactant chemicals for the oilwell industry.
Oil pumpjack, industrial equipment. Rocking machines for power generation. Extraction of oil. Oil well industry.

Surfactants are some of the most useful oilfield chemicals. Without them, oil drilling and fracking would be way less profitable and productive. Surfactants help in oil recovery from the ground. A feat that would require many more complex processes to achieve without these crucial chemicals.

But the use of surfactants transcends the oil and gas industry. These industrial chemicals are so important that they have critical uses across various fields. We use surfactants in soaps and detergents, lubricants, anti-fogging liquids, adhesives, fabric softeners, herbicides, emulsifiers, pharmaceutical formulations, cosmetics, and inks. Even the human body produces its surfactants.

Here in this article, you’ll learn everything you need to know about this widely useful chemical, including:

  • What surfactants are, why they are so important in and out of the oilfield, and how they work.
  • The benefits of surfactants.
  • How safe surfactants are for the environment.
  • And finally, the safe and reliable way to ship surfactants.

What Are Surfactants?

The name “surfactant” was originally coined from “Surface Active Agent”. This name suggests that surfactants act on surfaces. And in this case, the surfaces that surfactants act on are two phases that would normally not mix (like oil and water). It reduces the surface tension between the two phases so that the phases are more likely to mix.

You have surfactants in your house, and you probably don’t even know it. Most detergents, shampoos, lubricants, and other everyday chemicals usually have surfactants in them.

Surfactant chemical pipe and valve closeup
Surfactant pipe and valve close up next to an aboveground oil producing tower

How Surfactants Work

Surfactants have unique properties that make them useful for various purposes. The molecules of the chemicals have two distinct parts; water-soluble and water-insoluble. This property allows surfactants to fit perfectly in between different phases, lower their surface tensions, and make it more likely for them to mix.

Have you tried washing an oily plate with just water? Or tried to wipe a spilled jar of mayonnaise clean? The plate still ends up oily because the water just washes over the surface of the oil. But when you add a detergent that has a surfactant in it, it makes the oil mix better with the water, making it easy to wash off.

Now, scale it up to the level of cleaning up oil spills at oilfields. With the help of surfactants, oil recovery becomes enhanced and less wasteful.

Benefits of Surfactants

You may already have an idea about the benefits of surfactants from what now know about what the chemicals are and how they work. But here are more detailed benefits of surfactants.

1.    Surfactants Boost Cleaning Effectiveness

Cleaning agents, such as detergents, have surfactants in them to make cleaning more effective. Without surfactants in them, detergents would not mix with water, and cleaning would be stressful.

2.    Eases Lubrication

Shaving creams have surfactants in them to reduce friction and ease the movement of the razor over the skin while reducing irritation. Lubricants in car engines also use surfactants to prevent particles from accumulating on the engine parts.

3.    Saves Costs on the Oilfields

The use of surfactants in oilfields may be one of the most important uses of the chemicals. Cleaning up oil spills and recovering oil from the ground would require a lot of complex processes to complete without surfactants. And the more the processes are, the more oil companies spend.

Are surfactants Safe for the Environment?

All oilfield chemicals are subject to this question from the ever-scrutinizing hands of the environmental conservationists. And this is not surprising, as the oil drilling process involves a lot of processes and the use of chemicals that are not environment-friendly. But what about surfactants? Are they safe for the environment?

Thankfully, the American Cleaning Institute has invested time and resources into shedding light on this age-long debate. This investment is just another on the long list of contributions the body has made over years in a bid to promote environmental sustainability. They do this by inventing and improving approaches and tools to manage industrial chemicals, such as surfactants.

During the research, over 250 studies were carried out on the environmental toxicity and properties of four key high-volume surfactant classes. These surfactant classes are mostly used in various cleaning and personal care products. The conclusion was a positive one. The authors of the research paper concluded “that risk assessments demonstrate that these substances, although used in very high volume and widely released to the aquatic environment, have no adverse impact on the aquatic or sediment environments at current levels of use.”

How to Ship Surfactants

As it is with other chemicals, the shipping of these chemicals is just as important as the chemicals themselves. No one can use them if there aren’t ways to ship the surfactants from the manufacturers to the end-users. And so, the need for an appropriate shipping system for surfactants cannot be overemphasized.

Depending on the quantity of surfactants being shipped, the shipping methods of surfactants vary. Shippers tend to make use of drums or IBC totes to ship and ensure the long-term storage of small quantities of surfactants in liquid form. But the liquid bulk shipping of surfactants for industrial uses may use liquid bulk tanker trucks.

During this liquid bulk surfactant shipping, thousands of gallons of the chemicals are loaded into Stainless Steel Insulated (SSI) tanker trucks. And the trucks are manned by liquid chemical drivers who have adequate experience in safely transporting the chemical to their destinations. However, this sort of transport comes with its complications.

Challenges of Shipping Liquid Surfactants in Bulk

The major challenge that confronts the shipping of bulk liquid surfactants is the fact that surfactants are classified as hazardous materials. And the transport of hazardous materials comes with a lot of regulations and complications. These regulations are necessary because an accident involving hazardous surfactants could have severe impacts on the environment.

For instance, surfactants in their raw forms have negative reactions when they come in contact with human skin. And the reactions could worsen if consumed. So, this classification of surfactants as hazardous materials is an attempt by the United States to make the transport of the chemicals as safe as can be under the guidance of rules and regulations.

It however takes an experienced liquid chemical carrier to successfully transport the chemicals to their destinations hitch-free. The liquid chemical carrier needs to have the proper hazardous material certifications, a sixth sense familiarity with the regulations, and the proper hazmat transport training and equipment. Without these, the carrier and the chemical owners are liable to penalties from the bodies in charge of the shipping.

Only a few liquid bulk carriers qualify to handle this delicate task of shipping these highly dangerous chemicals, and Total Connection liquid bulk tanker carriers are among the few.

Ship Your Surfactants With Total Connection

Ship surfactant chemicals with Total Connection

Total Connection is a logistics company with over 20 years shipping oilfield and industrial chemicals all over the world. We have forged partnerships with the world’s leading distributors of surfactants, oil companies, and other industries to minimize your shipping costs by shortening your supply chain.

In our two-decades-plus of experience shipping surfactants, we have handled different complications and challenges, and we have mastered the job to the point of perfection. All you need is to fill the quote form below and our industrial chemical shipping experts will be in touch with you.

Filed Under: Liquid Bulk Shipping, Oil and Gas

Oilfield Chemicals Shipping: Drilling Fluids and Additives

February 17, 2021 by luis uribe

There is a major dilemma surrounding drilling and fracking for oil and gas. On one hand, humankind can hardly survive without this source of energy. Our survival hinges on it. But on the other hand, the oil drilling and fracking processes have many adverse effects on the environment. All sorts of drilling chemicals are injected into the ground to boost the production of oil, degrading the environment around the drilling site. And this has got environmental activists going on and on about these detrimental effects.

There is a major dilemma surrounding drilling and fracking for oil and gas. On one hand, humankind can hardly survive without this source of energy. Our survival hinges on it. But on the other hand, the oil drilling and fracking processes have many adverse effects on the environment. All sorts of drilling chemicals are injected into the ground to boost the production of oil, degrading the environment around the drilling site. And this has got environmental activists going on and on about these detrimental effects.

Amongst these oil drill-optimizing chemicals are drilling fluids and additives. In this article, you’ll see:

  • What drilling fluids and additives are, and why we use them in the oilfield.
  • The different types of drilling fluids and additives.
  • What you need to know about shipping these oilfield chemicals, including the challenges that befall them.
  • And how Total Connection oilfield chemical logistics company is a solution to these challenges.

Drilling Fluids and Additives: What They Are Why We Use Them

oilfield drums stacked and filled with drilling fluids.

Drilling fluids, or drilling muds, are oilfield chemicals that help to ease the drilling of wellbores deep into the ground. And as the name suggests, operators add drilling fluid additives to drilling muds to help to boost the effectiveness of the drilling fluids. The combination of drilling fluids and additives makes the oil drilling process more efficient, while mitigating the environmental impacts and ultimately saving costs.

The needs of each oilfield are unique, depending on location, size of the operation, how challenging the job is, and many other factors. As a result, the fluid and additives used in oil production are numerous to help cater to these various needs in the oilfield.

The Different Types of Drilling Fluids and Additives

There is a long list of drilling fluids and additives types, with each serving a unique purpose in the highly complex drilling process. The following are the different types of drilling fluids and additives we use in oilfields.

Fluid Loss Control Agents

When drilling fluids are injected into wellbores to force oil out of fractures, the turbulence down there could lead to the loss of fluids. This is bad because uncontrolled fluid loss bears grave consequences on the environment. As a result, it is important to use fluid loss control agents to control the escape of drilling fluids into places they shouldn’t get to.

Defoamers

Some unwanted gases try to escape to the surface during the oil drilling process. These gases could drop the effectiveness of drilling fluids by a huge margin when they mix with the fluids. The muds then begin to foam to show that a lot of gases have been trapped within. That is why there is the need for defoamers. Defoamers are mud additives used to release the trapped gases in the drilling mud to send unwanted gas up to the surface.

Drilling Fluid Additives

Not only is oil drilling complex, but it’s also delicate. Too much alkalinity or acidity could ruin the entire process. That’s what oil producers invest in drilling fluid additives which help to adjust and regulate the pH levels of the drilling fluids. These chemicals keep the acidity and alkalinity of the drilling muds under control.

Alkalinity Control

Alkalinity control chemicals are similar to drilling fluid additives. They also help to regulate the pH level of the drilling muds. Examples of alkalinity control chemicals include citric acid, soda ash, lime, lime O, magnesium oxide, sodium bicarbonate, potassium hydroxide, caustic soda, and more.

Emulsifiers and Wetting Agents

Injecting drilling fluids at high rates could cause a lot of instability in the wellbores if there aren’t some chemicals in the drilling fluids. Examples of such chemicals are emulsifiers and wetting agents. Emulsifiers and wetting agents help reduce the surface tension in drilling fluids to improve their penetrating and spreading properties.

Pipe-Freeing Agents

Friction in pipes is also another problem that might have caused a lot of problems for oil drilling companies if there weren’t pipe-freeing agents. The drilling fluid could stick to some parts of the pipe and reduce fluid flow until it completely blocks the pipe. This is especially common in pipes that are angled in deviated wellbores. To combat the situation, oil companies use pipe-freeing agents. Examples of pipe freeing agents include soaps, glass beads, oils, surfactants, soda lime, cationic polyacrylamide, and many more.

Lubricants

It’s no news that friction could be a major oil drilling problem if untended. Fortunately, there are many oilfield chemicals that help to combat it. An example of such chemicals are lubricants. Lubricants help to reduce drag and torque in the drill bit, thereby putting all the generated horsepower to effective work. Examples of lubricants include diesel oil, different kinds of vegetable oils, fatty acid esters, graphite powder, asphalt blends, soaps, air-blown asphalt colloids, and many more.

Oilfield drilling lubricants

Temperature Stabilizers

Oilfields in high-temperature regions always need to maintain thermal stability. There is also the need to boost the stability of the filtration and rheological properties of the drilling fluids. We use temperature stabilizers in oilfields for these two main reasons.

Viscosifiers

There are some drilling situations where high viscosity drilling fluids are needed. And this often happens when there are rock cuttings to float to the surface from the wellbores. Since rock cuttings might not float well in low viscosity fluids, viscosifiers are needed to increase the viscosity of the drilling fluids. A common viscosifier example is clay. Some fluid loss control agents may also double as viscosifiers.

Surfactants

The use of surfactants is similar to that of emulsifiers and wetting agents. Surfactants reduce the interfacial tension between water and the surfaces it comes in contact with inside the wellbore, including oil, air, and solids.

Friction Reducers

Friction reducers help to reduce the high friction pressures that are generated from the rapid and powerful injection of drilling fluids into wellbores. There is so much more about this oilfield chemical. Our article on friction reducers tells you everything you need to know about them.

Shipping Bulk Drilling Fluids and Additives for Oilfields

These drilling fluids are very important in the oilfield, and oilfields cannot do without them. A drilling site has to have these chemicals ready for use because millions of dollars could be lost otherwise. And that is why oil producers often knit close partnerships with the oilfield chemical logistics companies.

Challenges of Shipping Liquid Bulk Fluids and Additives for Oil Fields

Every oil company wants one thing amongst many others: a comprehensive logistics and distribution management system that helps them optimize cost and reduce out-of-stock situations. But this is a major challenge for the oil companies, as achieving this aim is easier said than done. There are just so many parties involved in the coordination of these supply chains. For instance, a supply chain would need inventory supervisors, site foremen, purchasing directors, third-party freight managers, carriers, shipping warehouse managers, and that’s just naming a few.

Another challenge that confronts oil companies is the usually vast sizes of the oilfields, with some being hundreds of miles wide in size. This is a problem because oil and gas drilling has not evolved to a level of complete technological automation. Everything has to be done manually.

And operators carry out so much chemical monitoring manually, they have to rely on their field experience and tools that are prone to error from years of use. But with nothing but their experience and these inaccurate tools, operators have to monitor chemical stock levels, injection rates, chemical supply, and production rates. These responsibilities are hard to lay on the shoulders of experience alone, as production rates are often inconsistent and forecasting becomes difficult.

Without putting proper planning and a reliable oilfield chemical logistics company in place, the consequences would be dire. A timeout of a few hours on the part of the logistics company could lead is too much time to waste. That is why it is best to partner with an experienced and reliable oilfield chemical logistics company, such as Total Connection.

Shipping Your Oil Fields Drilling Fluids and Additives with Total Connection

Total connection offers you something many other logistics companies struggle with. One of them is experience. We aren’t just talking about general logistics experience. Anyone can offer you that. We’re talking about hardcore experience in shipping oilfield chemicals to drilling sites effectively, efficiently, and reliably on a routine basis. Total Connection has almost three decades of experience in that. And in that time, we have worked with budding oil companies to the largest oil production companies with sustained success.

From experience, we are already familiar with all the possible challenges that may befall your oil production company. And we have the skills and networks that foresee and minimize your risks because of these challenges. With these skills and networks, we have forked out significant opportunities that remain unknown to other logistics companies, to save you costs while minimizing the likelihood of out-of-stock situations.

Let us know how we can help tighten up your oilfield drilling fluid and additives supply chain. Start by filling out the quote form below. We’ll be glad to partner with you.

Filed Under: Liquid Bulk Shipping, Oil and Gas

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